talk about
1 This can be considered the short version of When you talk about xxx, nothing is more xxx than this/him/her/them/you! This is an exclamation and should have an exclamatory intonation. One peculiarity about this expression is that it's (almost) always sincere, unlike, for example, What a xxx! or How xxx!, which can be used sarcastically.
For instance, if someone tells you about something especially nasty that their boss did, you could answer sarcastically What a sweetheart! or How nice! when you actually mean the opposite. However, if you use talk about, you normally say exactly what you mean: Talk about a jerk!
Two coworkers talk about their boss getting arrested.
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Ron: Hey, is it true that Mr. Wagner got arrested for stealing from the company?
Dave: Yep. They caught him on camera red-handed taking fistfuls of money out of the safe.
Ron: But wait… he knows there are surveillance cameras all over the office.
Dave: Yeah, but get this… he actually thought that if he put on his sunglasses, nobody would recognize him.
Ron: <gasp!> Talk about a moron!
2 The phrase talk about can also be followed by an adjective, in which case it has an interpretation of How/So very [ADJ]! In the snippet below, and talk about smart! basically means ...and she's soooo smart!
Hugh tries to set his son up with a coworker’s daughter.
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Hugh: Pauly, have I got a girl for you!
Pauly: Oh God, here we go! When are you going to stop trying to set me up with your friends’ boring-ass daughters?! Has it ever occurred to you that maybe I want to be single?
Hugh: Oh but this one’s different. She’s a ballerina, drop-dead gorgeous, and talk about smart! She opened her own dance studio last year, and she’s making an absolute mint!
3 Sometimes talk about is used with idioms and expressions to highlight situations that are perfect examples of those idioms. For instance, we have the expression to rob the cradle, which means to be romantically involved with someone way younger — literally, to steal a baby out of its cradle. In the following snippet, talk about robbing the cradle means something along the lines of «what a PERFECT EXAMPLE of robbing the cradle!» The same with green thumb in the second snippet.
Ron and Adam see their old boss and their young coworker at the company Christmas party.
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Ron: What the hell’s Cooper doing holding Vicky’s hand?
Adam: Wait… you don’t know? They’re dating. They’ve been dating for 2 months.
Ron: Shut up! Isn’t he like twice her age?
Adam: Try three times.
Ron: Yuck! Talk about robbing the cradle!
Hugh arrives in Dallas to spend a week at his brother's place.
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Hugh: Man! Your place is beautiful!
Christian: You haven't seen the best part. Come see the garden.
Hugh: Wow! This is amazing! Did you plant all this yourself?
Christian: Yep.
Hugh: Talk about a green thumb!